They had not been demonstrated experimentally, to be sure; but they were still the default projection from what was already known.
What I am guessing happened (you’re welcome to research the topic), first you can learn that uranium can be fissioned by neutrons (which you make, if I recall correctly, by irradiating lithium with alpha particles). Then, you may learn that fission produces neutrons, because, it so happens that you don’t just see all of that in microscope, you see particle tracks in photographic emulsion or a cloud chamber or the like, and neutrons, being neutral, are hard to detect. (edit: And this is how I read the quote, anyway, on the first reading. I just parse it as low probability of neutrons, high probability of chain reaction if there’s enough neutrons.)
So at first you do not know if fission produces neutrons without very precise and difficult analysis of the conservation of momentum or a big enough experiment to actually be able to count them, or something likewise clever and subtle. To think about it, chronologically, you may happen to first acquire weak evidence that fission does not produce prompt neutrons, by detecting beta decay from the fission products, which implies that they still have too many neutrons for their atomic number. And perhaps by detecting recoil from the delayed neutrons (which are too few for chain reaction, and are too delayed for a bomb).
Why didn’t it work on Reality?
Or did it? It’s bit like arguing how dumb it was to predict 1⁄6 probability for the die rolling 1, when it in fact rolled 1. Given 6 other sides and lack of information to prefer one over the other, the probability is 1⁄6 (edit: or less, of course) . The relevant reality here is the available knowledge and the mechanism that assigns plausibilities, and the first step of “working” is probabilities (somehow related to plausibilities) summing to 1. You ought to be able to test a mind upload’s priors—just run them in parallel a very large number of times, having them opinion about probabilities of various topics, and see to what mutually exclusive scenarios sum, or if the sum even converges. Ghmm.
Ohh, the elephant in the room that I somehow neglected to mention. (It is hard to argue against silly ideas, I suspect for a reason similar to why it is very hard / impossible to truly reflect on how you visually tell apart cats and dogs)
There’s a lot of nuclei that can fission, but can’t sustain a chain reaction! Because they do not produce high enough energy neutrons, or they capture neutrons too often and fission too rarely, and so on. And the neutron source of the time (radium plus lithium, or radium plus beryllium, or something like that), it produced a lot of high energy neutrons.
It would be quite interesting if someone far more obsessive compulsive than me would go over the table of isotopes and see if about 1 in 10 isotopes that can fission when irradiated with radium-lithium or radium-beryllium neutron source produce enough neutrons of high enough energy. Because if it is close to 1 in 10, and I think it is (on appropriate, i.e. logarithmic, scale), then the evidence that one isotope can fission, will only get you to 1 in 10 chance that it makes neutrons that can fission it.
Szilard was proposing the idea of fission chain reactions in general. Of course he would be less confident if asked about a specific isotope, but he’s still right that the idea is important if he gets the isotope wrong. Anyway, the fact that he discusses uranium specifically shows that the evidence available to him points toward uranium and that this sort of reference class is not using all the evidence that they had at the time.
and that this sort of reference class is not using all the evidence that they had at the time.
You’re making it sound like you have a half of the periodic table on the table. You don’t. There’s U-238, U-235, Th-232, and that’s it . Forget plutonium, you won’t be making any significant amount of that in 1945 without a nuclear reactor. Of them the evidence for fission would be coming, actually, from U238 fissioning by fast neutrons, and U238 can’t sustain chain reaction because too many of the the neutrons slow down before they fission anything, and slow neutrons get captured rather than cause fission.
U235 is the only naturally abundant fissile isotope, and it has a half life of 700 million years, which is 4400 times longer than the half life of the second most stable fissile isotope (U-233) and 30 000 longer than that of the third most stable isotope (that’s it. The factor of 4400 difference, then the factor of less than 7 , and so on). That’s how much U235 is a fluke. One can legitimately wonder if our universe is fine tuned for U235 to be so stable.
edit: note, confusing terminology here: “fissile” means capable of supporting a chain reaction, not merely those capable of fissioning when whacked with a high energy neutron.
edit2: and note that the nucleus must be able to capture a slow neutron and then fission due to capturing it, not due to being whammed by it’s kinetic energy, contrary to what you might have been imagining, because neutrons lose kinetic energy rather quickly, before sufficient chance at causing a fission. It must be very unstable, yet, it must be very stable.
I’m correcting a potential factual error:
What I am guessing happened (you’re welcome to research the topic), first you can learn that uranium can be fissioned by neutrons (which you make, if I recall correctly, by irradiating lithium with alpha particles). Then, you may learn that fission produces neutrons, because, it so happens that you don’t just see all of that in microscope, you see particle tracks in photographic emulsion or a cloud chamber or the like, and neutrons, being neutral, are hard to detect. (edit: And this is how I read the quote, anyway, on the first reading. I just parse it as low probability of neutrons, high probability of chain reaction if there’s enough neutrons.)
So at first you do not know if fission produces neutrons without very precise and difficult analysis of the conservation of momentum or a big enough experiment to actually be able to count them, or something likewise clever and subtle. To think about it, chronologically, you may happen to first acquire weak evidence that fission does not produce prompt neutrons, by detecting beta decay from the fission products, which implies that they still have too many neutrons for their atomic number. And perhaps by detecting recoil from the delayed neutrons (which are too few for chain reaction, and are too delayed for a bomb).
Or did it? It’s bit like arguing how dumb it was to predict 1⁄6 probability for the die rolling 1, when it in fact rolled 1. Given 6 other sides and lack of information to prefer one over the other, the probability is 1⁄6 (edit: or less, of course) . The relevant reality here is the available knowledge and the mechanism that assigns plausibilities, and the first step of “working” is probabilities (somehow related to plausibilities) summing to 1. You ought to be able to test a mind upload’s priors—just run them in parallel a very large number of times, having them opinion about probabilities of various topics, and see to what mutually exclusive scenarios sum, or if the sum even converges. Ghmm.
Ohh, the elephant in the room that I somehow neglected to mention. (It is hard to argue against silly ideas, I suspect for a reason similar to why it is very hard / impossible to truly reflect on how you visually tell apart cats and dogs)
There’s a lot of nuclei that can fission, but can’t sustain a chain reaction! Because they do not produce high enough energy neutrons, or they capture neutrons too often and fission too rarely, and so on. And the neutron source of the time (radium plus lithium, or radium plus beryllium, or something like that), it produced a lot of high energy neutrons.
It would be quite interesting if someone far more obsessive compulsive than me would go over the table of isotopes and see if about 1 in 10 isotopes that can fission when irradiated with radium-lithium or radium-beryllium neutron source produce enough neutrons of high enough energy. Because if it is close to 1 in 10, and I think it is (on appropriate, i.e. logarithmic, scale), then the evidence that one isotope can fission, will only get you to 1 in 10 chance that it makes neutrons that can fission it.
Szilard was proposing the idea of fission chain reactions in general. Of course he would be less confident if asked about a specific isotope, but he’s still right that the idea is important if he gets the isotope wrong. Anyway, the fact that he discusses uranium specifically shows that the evidence available to him points toward uranium and that this sort of reference class is not using all the evidence that they had at the time.
You’re making it sound like you have a half of the periodic table on the table. You don’t. There’s U-238, U-235, Th-232, and that’s it . Forget plutonium, you won’t be making any significant amount of that in 1945 without a nuclear reactor. Of them the evidence for fission would be coming, actually, from U238 fissioning by fast neutrons, and U238 can’t sustain chain reaction because too many of the the neutrons slow down before they fission anything, and slow neutrons get captured rather than cause fission.
U235 is the only naturally abundant fissile isotope, and it has a half life of 700 million years, which is 4400 times longer than the half life of the second most stable fissile isotope (U-233) and 30 000 longer than that of the third most stable isotope (that’s it. The factor of 4400 difference, then the factor of less than 7 , and so on). That’s how much U235 is a fluke. One can legitimately wonder if our universe is fine tuned for U235 to be so stable.
edit: note, confusing terminology here: “fissile” means capable of supporting a chain reaction, not merely those capable of fissioning when whacked with a high energy neutron.
edit2: and note that the nucleus must be able to capture a slow neutron and then fission due to capturing it, not due to being whammed by it’s kinetic energy, contrary to what you might have been imagining, because neutrons lose kinetic energy rather quickly, before sufficient chance at causing a fission. It must be very unstable, yet, it must be very stable.